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dc.contributor.advisorCauzzi, Daniele Alessandro-
dc.contributor.authorAndreo, Jacopo-
dc.description.abstractThe nucleophilic addition of aminophosphanes to alkyl- and aryl- isothiocyanate leads to the formation of the zwitterionic thioamidyl-phosphonium (P+C(S)N−R) functional group. Within this family of its compounds, EtNHC(S)Ph2PNPPh2C(S)NEt (HEtSNS) can be prepared by reacting Ph2PNHPPh2 (dppa) in EtNCS as the reaction medium. In this thesis, we present a comparison between various metal complexes families and how this exceptionally flexible ligand adjust itself to best fit the metal requirement as a function of the metal centre and chemical conditions of the
dc.publisherUniversita' degli studi di Parma. Dipartimento di Scienze chimiche, della vita e della sostenibilità ambientaleit
dc.relation.ispartofseriesDottorato di ricerca in Scienze chimicheit
dc.rights© Jacopo Andreo, 2020it
dc.subjectzwitterionic metallatesit
dc.subjectpalladium coordination compoundsit
dc.subjectcobalt coordination compoundsit
dc.titleZwitterionic coordination compounds: synthesis and characterization of Co and Pd metallatesit
dc.typeDoctoral thesisit
Appears in Collections:Scienze chimiche, Tesi di dottorato

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