Please use this identifier to cite or link to this item: https://hdl.handle.net/1889/1615
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dc.contributor.advisorCatellani, Marta-
dc.contributor.authorMaestri, Giovanni-
dc.date.accessioned2011-07-14T09:17:23Z-
dc.date.available2011-07-14T09:17:23Z-
dc.date.issued2011-
dc.identifier.urihttp://hdl.handle.net/1889/1615-
dc.description.abstractNovel synthetic applications of the Palladium/norbornene catalytic system are presented herein. Selective aromatic and aliphatic (or heteroaromatic) C-H bond activation in sequence allowed to present two new methods featuring intramolecular C-C bond formation. Development of one of this method employing alpha nitro esters allowed to find a novel method for the synthesys of aryl nitriles in the absence of a cyanide source. DFT calculations on this unsual reactivity proposes that the reaction occours through a Pd-mediated retro Mannich reaction. Mechanistic study on Pd/norbornene catalyzed sequences by DFT calculations allowed to enlight the role of substituents on the reacting aryl halides, which triggers the formation of Pd(IV) complexes responsible for selective biaryl synthesis.it
dc.language.isoIngleseit
dc.publisherUniversità degli Studi di Parma. Dipartimento di Chimica Organica e Industrialeit
dc.publisherUniversità degli Studi di Parma. Dipartimento di Chimica Generale e Inorganica, Chimica Analitica, Chimica Fisicait
dc.relation.ispartofseriesDottorato di ricerca in Scienze Chimicheit
dc.rights© Giovanni Maestri, 2011it
dc.subjectPalladiumit
dc.subjectCatalysisit
dc.subjectDFTit
dc.subjectCross-couplingit
dc.subjectC-H activationit
dc.titleThe Palladium/norbornene catalytic system: novel synthetic applications and mechanistic insightsit
dc.typeDoctoral thesisit
dc.subject.miurCHIM/04it
dc.description.fulltextopenen
Appears in Collections:Scienze chimiche, Tesi di dottorato

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